Apparatus and oil compositions containing olefin dimer products

ABSTRACT

Heat transfer, lubricating, functional and/or insulating fluid compositions for use in apparatus such as electrical transformers contain up to 25 weight percent of one or more oil additives and a 1-octene and/or 1-decene dimer and/or a 1-octene and 1-decene co-dimer oil having improved low temperature properties which oil contains less than about 2.5 weight percent of, respectively, the 7-methylpentadecene, 9-methylnonadecene and, 7- and 9-methylheptadecene isomers. The dimers can be hydrogenated to provide the saturated counterparts of the isomers.

RELATED APPLICATION

This application is a Continuation-in-Part of application Ser. No. 684,291, filed Apr. 12, 1991, now abandoned, entitled Olefin Dimer Products which is a continuation-in-part of application Ser. No. 554,727, filed July 19, 1990, now U.S. Pat. No. 5,068,487 both of which applications are incorporated herein by reference.

BACKGROUND

This invention relates generally to alpha-olefin oligomers which are useful as synthetic lubricants and functional fluids and more particularly to apparatus and fluids which contain alpha-olefin dimer products having improved low temperature properties which can be prepared by a BF₃ -promoter catalyst system using alcohol alkoxylates as promoters.

Alpha-olefin oligomers and their use as synthetic lubricants ("synlubes") are well-known. The oligomers are usually hydrogenated in order to improve their stability. Early reports of such synlubes are in Seger et. al. U.S. Pat. No. 2,500,161 and Garwood U.S. Pat. No. 2,500,163. The particular applications for which such oligomer oils are used depends upon their viscosity, with viscosities of about 2-10 cSt at 100° C. being preferred for general lubricating oil applications. Low viscosity, (e.g. 1-3 cSt at 100° C.) alpha-olefin dimer oils are especially useful in heat transfer, insulating, hydraulic and low temperature lubricant applications.

Co-pending Application Serial No. 554,727 describes a process for preferentially making dimer oils of linear alpha-olefins such as 1-octene and 1-decene by using a catalyst comprising boron trifluoride and an alcohol alkoxylate promoter such as 2-methoxyethanol. This process produces dimer products which have improved low temperature properties compared to dimers prepared using other alcohol promoters such as propanol or butanol. These dimer products of 1-decene or 1-octene remain clear, without precipitation of components at -54° C. The products have a unique isomer content in that they contain undetectable amounts (less than about 0.5% by weight) of, respectively, the nearly straight chain isomers 9-methylnonadecenes and 7-methylpentadecenes or, after hydrogenation of the dimer products, the saturated counterparts of these compounds. In contrast, commercially available hydrogenated dimers prepared, for example, by oligomerizing 1-decene using a BF₃ -butanol, or BF₃ -propanol catalyst have a significantly different isomer content than those produced using the alcohol alkoxylate promoters and contain much greater amounts (3 to 5 weight percent) of relatively linear isomers, e.g. 9-methylnonadecane, and become cloudy and exhibit significant viscosity changes at -54° C.

BRIEF SUMMARY

In accordance with this invention there is provided an apparatus containing a heat transfer, lubricating, functional and/or insulating fluid which comprises a dimer of 1-octene which is a mixture of C₁₆ H₃₂ isomers containing less than about 2.5 weight percent of 7-methylpentadecene isomers and/or a dimer of 1-decene which is a mixture of C₂₀ H₄₀ isomers containing less than about 2.5 weight percent of 9-methylnonadecane isomers and/or a co-dimer of 1-octene and 1-decene which is a mixture of C₁₈ H₃₆ isomers containing less than about 2.5 weight percent of the 7-methylheptadecene and/or 9-methylheptadecene isomers.

Also provided is a heat transfer, lubricating, functional and/or insulating fluid composition which comprises (i) a 1-octene and/or a 1-decene dimer and/or a 1-octene and 1-decene co-dimer oil comprising a mixture of isomers which in the case of the 1-octene dimer are C₁₆ H₃₂ isomers containing less than about 2.5 weight percent of the 7-methylpentadecene isomers, in the case of the 1-decene dimer are C₂₀ H₄₀ isomers containing less than about 2.5 weight percent of the 9-methylnonadecene isomers, and in case of the co-dimer are C₁₈ H₃₆ isomers containing less than about 2.5 weight percent of the 7-methylheptadecene and/or 9-methylheptadecene isomers, and (ii) from about 0.1 to 25 weight percent of fluid composition of one or more oil additives. The dimers can be hydrogenated to provide the saturated counterparts of the isomers, i.e. C₁₆ H₃₄ for the 1-octene dimer, C₁₈ H₃₈ for the co-dimer and C₂₀ H₄₂ for the 1-decene dimer.

DETAILED DESCRIPTION

The dimer products useful in this invention are preparable by the process described in co-pending application Ser. No. 554,727. According to the process, the 1-octene or 1-decene linear alpha-olefin monomer or a mixture of such monomers in any proportions is contacted with a catalytic amount of boron trifluoride which should be at least about 0.002 moles per mole of olefin. When a mixture of 1-octene and 1-decene is dimerized some 1-octene and 1-decene dimers are produced besides the co-dimer. Such mixtures can be employed in the invention without separating out the co-dimer. Preferably the reaction mixture is saturated with BF₃. The boron trifluoride is used in combination with a promoter which is an alcohol alkoxylate. This promoter surprisingly favors the production of lower oligomers and particularly products containing predominantly dimer and trimer with a dimer to trimer ratio of greater than about one. Under ordinary reaction conditions the dimer does not further react, and particularly does not dimerize, to any significant extent so that the reaction is easily controllable to produce a large proportion (at least about 40 and preferably 50 to 85 weight percent or more dimer based on the total weight of oligomers in the product) of dimer. The dimer content asymptotically approaches a maximum rather than sharply peaking at a transient maximum, which is common in prior processes. The dimer products are a complex mixture of 25 or more isomers (a C₂₀ H₄₂ paraffin can theoretically have 366,319 possible isomers). There is no absolute method for predicting the isomers most likely to be found in the hydrogenated dimer products of 1-decene products. Accordingly, analysis of all of the isomers by gas chromatography is not practical, especially since peaks can be mixtures of closely related isomers (see Onopchenko, et. al., "BF₃ -Catalyzed Oligomerization of Alkenes: Structures, Mechanisms, and Properties", Ind. Eng. Chem. Prod. Res. Dev. 1983, 22, 182-191). However, it is possible to identify the more linear isomers such as those having no branches or a single branch with one carbon atom. The dimer products prepared using the alcohol alkoxylate promoters have improved low temperature properties because of their unique isomer content in that they contain less than about 2.5 weight percent and, especially, less than about 0.5 weight percent of relatively linear isomers.

Alcohol alkoxylates useful in the invention can be represented, for example, by the formula:

    RO(CHR'--CHR''--(CHR''').sub.m --O).sub.n H

where m is 0, 1 or 2, R is hydrocarbyl containing from 1 to 24 carbons, including mixtures thereof, R', R'' and R''' are independently hydrogen, methyl, or ethyl and when m is 2, each R''' can be different, and n averages 1 to 15.

Examples of such alcohol alkoxylates include glycol ethers such as ethylene glycol monomethyl ether (2-methoxyethanol) and propylene glycol monoethyl ether and the like and ethoxylates derived from mixed C₂ to C₂₄, preferably C₂ to C₁₈ and most preferably C₆ to C₁₂ straight chain alcohols. Suitable ethoxylates where R'' and R'' are hydrogen and m in the formula is 0, and n in the formula averages about 2 to 12, and preferably 3 to 6, are commercially available under the Ethonic trademark.

The promoters are used in minor, effective amounts, for example, from about 0.001 to 0.040 moles per mole of alpha-olefin monomer (0.1 to 4.0 mole percent). In general, the BF₃ is used in molar excess to the amount of promoter. This can be accomplished by using a closed reactor and a small BF₃ pressure over the reaction mixture. The promoter can be mixed with the olefin feed and the reaction can be carried out in a batch or continuous process at temperatures of about 0° to 200° C. and pressures ranging from atmospheric up to, for example, 1,000 psig. The reaction temperature will change the oligomer distribution with temperatures of about 50° C. and above favoring the production of lower oligomers, namely dimer. Preferred reaction temperatures and pressures are about 20° to 65° C. and 5 to 100 psig.

The oligomer mixture from the reaction contains monomer which can be removed by distillation. The monomer has been found to contain mostly less reactive, isomerized material. However, this monomer can be recycled because it will react to form oligomers in the presence of fresh alpha-olefin monomer. For example, portions of up to about 25 weight percent and preferably 5 to 15 weight percent recycled monomer based on total monomer can be mixed with fresh monomer. The product mixture can be further separated by distillation to provide one or more product fractions having the desired viscosities for use in various lubricant applications such as drilling, hydraulic or metal working fluids, gear oils and crankcase lubricants.

The alcohol alkoxylates in the presence of BF₃, form stable complexes which separate from the product mixture on standing and can be readily recovered and reused. This avoids the BF₃ separation and recovery procedures necessary when using, for example, a BF₃ -butanol complex. In fact, because the alcohol ethoxylates are surfactants, it is preferable to let the catalyst settle from the reaction mixture prior to quenching with base, and especially when using NaOH, in order to avoid the formation of an emulsion.

The oligomer product can be hydrogenated by conventional methods. Supported nickel catalysts are useful. For example, nickel on a Kieselguhr support gives good results. Batch or continuous processes can be used. For example, the catalyst can be added to the liquid and stirred under hydrogen pressure or the liquid may be trickled through a fixed bed of the supported catalyst under hydrogen pressure. Hydrogen pressures of about 100 to 1,000 psig at temperatures of about 150° to 300° C. are especially useful.

The preparation of the fluids for use in the invention is further illustrated by, but is not intended to be limited to, the following examples in which the oligomerizations are performed in a three pint stirred reactor consisting of a glass reactor bowl, glass jacket, and a stainless steel top. The reactor is equipped with an air driven magnetic drive stirrer with a marine propeller, a heating/cooling coil and circulating system, dip tube, gas inlet and outlet valves and a pressure relief valve.

EXAMPLES 1-5

1-Decene (600.0 grams, 4.29 moles) and 1.0 mole % based on 1-Decene of Ethonic® 610-3, (which is a C₆ to C₁₀ mixed alcohol ethoxylate having an average of three --CH_(2l) --CH₂ O --groups), are charged into the reactor which is then assembled and purged with N₂ with gentle agitation for 30 minutes. During this time the reactor is brought up to the appropriate reaction temperature by the heating coil circulating system. The reactor is then pressurized (N₂) to 20 psig to insure that no leaks exist. After the pressure is relieved the stirring rate is increased and BF₃ is introduced into the reactor via a sparge tube located below the surface of the liquid. After a brief (5-10 seconds) purge, the system is pressurized to 10 psig with BF₃. The reaction is stopped after the chosen reaction time by venting the BF₃ through a 10 weight percent NaOH scrubber and quenching with either 5% aqueous NaOH (Examples 2 and 3) or saturated Na₂ SO₄ (Examples 1, 4 and 5) (50-150 ml). The reactor is purged with dry N₂ until all of the BF₃ is removed. The polyalphaolefin (PAO) - unreacted decene mixture is washed several times with water, dried over anhydrous CaCl₂, and filtered. The product content is determined by gas chromatographic analysis. The reaction times, temperatures and product analysis are given in Table 1.

                  TABLE 1                                                          ______________________________________                                                       Temp.   GC                                                       Ex-   Time    (°C.)                                                                           Area %.sup.1                                             ample (min)   [Max.]  Monomer Dimer Trimer                                                                               Tetramer                             ______________________________________                                         1     120     20 [28] 11      41    42    6                                    2     120     32 [39] 15      48    32    4                                    3     120     45 [50] 23      48    20    9                                    4      60     45 [52] 29      50    19    3                                    5     120     80 [86] 14      68    16    3                                    ______________________________________                                          Where area % ˜ weight %                                            

EXAMPLE 6

The process of Example 2 is repeated except at double the amount of alcohol ethoxylate (4 wt %/2 mole %) and quenching is with saturated Na₂ SO₄. The product distribution in gas chromatography area percent is 9% monomer, 48% dimer, 37% trimer and 6% tetramer.

EXAMPLE 7

The process of Example 3 is repeated except that quenching is with saturated Na₂ SO₄ and 9.1 weight percent of the decene monomer is recycled, considerably isomerized monomer from a previous reaction. The product distribution in gas chromatography area percent is 20% monomer, 52% dimer, 24% trimer and tetramer.

EXAMPLE 8

The process of Example 2 is repeated except that Ethonic® 810-6 (2.8 wt %, 1.0 mole %) which is a C₈ to C₁₀ mixed alcohol ethoxylate having an average of six --CH₂ --CH₂ O--groups is used as the promoter and quenching is with saturated Na₂ SO₄. The product distribution in gas chromatography area percent is 24% monomer, 46% dimer, 26% trimer and 4% tetramer.

The dimer fractions from Examples 1, 2 and 3 are separated by distillation and hydrogenated. Their physical properties are reported in Table 2 where the composition is given in gas chromatography area percent.

                  TABLE 2                                                          ______________________________________                                         Example    1          2          3                                             ______________________________________                                         Monomer    --         0.5        0.7                                           Dimer      98.9       96.7       97.9                                          Trimer     1.1        2.6        1.4                                           Tetramer   --         0.2        --                                            KV.sub.100° C. (cSt)                                                               1.71       1.66       1.63                                          KV.sub.40° C. (cSt)                                                                5.22       4.99       --                                            KV.sub.-40° C. (cSt)                                                               266.0      251.0      257.0                                         Pour Point (°C.)                                                                   <-65       <-65       <-65                                          Flash Point (°C.)                                                                  160.0      148.0      152.0                                         ______________________________________                                    

EXAMPLE 0 A-E

This example illustrates the recycle of the promoter/-BF₃ co-catalyst complex.

1-Decene (600.0 g, 4.29 mol) and Ethonic® 610-3 ethoxylate (11.79 g, 42.9 mmol) are charged into the reactor which is then assembled and purged with N: with gentle agitation for 30 minutes; during this time the vessel temperature is brought up to 45° C. The reactor is then pressurized (N₂) to 20 psig to insure that no leaks exist. After the pressure is relieved, the stirring rate is increased and BF₃ is introduced into the reactor via a sparge tube located below the surface of the liquid. After a brief (5-10 seconds) purge, the system is pressurized to 10 psig with BF₃. Periodic samples are collected and quenched with saturated aqueous Na₂ SO₄, washed with water (twice), dried over anhydrous CaCl₂, filtered through syringe disk filters, and analyzed by gas chromatography.

After 60 minutes, the BF₃ is purged from the reactor with N₂ for about 30 minutes. The stirring is then stopped to allow the two existing phases to separate (˜20 minutes). The upper layer (product 9A) is then drained and washed with 5% aqueous NaOH followed by 2 water washes. The lower layer (co-catalyst) remains in the reactor.

At this point more 1-decene is added and a second reaction initiated by pressurizing the reactor with BF₃ (no 25 additional Ethonic®610-3 is added). After 60 minutes the mixture is again purged with N₂, allowed to settle (20 minutes), and the PAO drained (9B). This procedure is repeated once more to collect a third lot of PAO (9C).

After the third run, the co-catalyst layer is kept in the reactor under an atmosphere of BF₃ /N₂. After 20 hours another run (120 minutes) is made to collect a fourth lot of PAO (9D). Again, after an additional 20 hours, a fifth run is made (9E). Results are tabulated in Table 3.

                  TABLE 3                                                          ______________________________________                                                Time     GC Area %                                                      Reaction                                                                              (min)    Monomer    Dimer Trimer                                                                               Tetramer                                ______________________________________                                         9A     60       26         50    21    3                                       9B     60       44         42    12    1                                       9C     60       46         41    12    1                                       9D     120      29         54    16    2                                       9E     120      34         50    14    1                                       ______________________________________                                    

The results illustrate that the co-catalyst can be easily recycled an remains effective in providing high yields of dimer.

EXAMPLE 10

Example 3 is repeated using 2-methoxyethanol promoter at a concentration of 1 mole percent based on monomer. After two hours the gas chromatography area percent product distribution is 8% monomer, 77% dimer, 13% trimer and 2% tetramer or about 85% dimer based on total oligomer product with a conversion to oligomer of over 90%. Repeating the process at double the promoter concentration [2.0 mol % (1.0 wt %)] gave about the same result in half the time (one hour instead of two). This example illustrates that an oligomer which is close to a 2 cSt (at 100° C.) viscosity product can be produced by merely removing the monomer.

COMPARISON

A product prepared from 1-decene monomer using a BF₃.N-BUTANOL catalyst (1.3 mole percent n-butanol on monomer) at a reaction temperature of 40° C. and 20 psig Bf₃ pressure typically gives a gas chromatography area percent product distribution of about 1% monomer, 2% dimer, 53% trimer, 28% tetramer, 11% pentamer, and 5% hexamer.

Samples of eicosane (linear C₂₀) and 9-methylnonadecane were obtained. The 9-methylnonadecane was synthesized by the dimerization of 1-decene using tri-n-octyl aluminum followed by hydrogenation. This procedure is known to give 9-methylnonadecane as the predominant C₂₀ product. A sample of 2-methoxyethanol generated hydrogenated decene dimer prepared according to Example 10 was spiked with eicosane and 9methylnonadecane and analyzed by gas chromatography. No 9-methylnonadecane isomer was detected (less than 0.5 weight percent) in the unspiked sample. The retention time of the 9-methylnonadecane was the same as the relatively linear isomer in the 1-butanol/1-propanol generated material. Subsequently, GC/MS analysis confirmed that this isomer was 9-methylnonadecane. No eiscosane was observed in either product.

Samples of the 2-methoxyethanol generated dimer were then spiked with varying amounts of 9-methylnonadecane and the KV₋₅₄° C. values determined with the results shown below:

                  TABLE 4                                                          ______________________________________                                                % Isomer  KV.sub.-54° C.                                                                    Kv.sub.-54° C.                               Entry  Added     (20 min)  Final   Comments                                    ______________________________________                                         A      0%        1030 cSt  1030 cSt                                                                               Clear, no vis.                                                                 change                                      B      1%        1070 cSt  1060 cSt                                                                               Sl. cloudy, 1.5                                                                hour                                        C      3%        2110 cSt  1160 cSt                                                                               Cloudy - 15                                                                    minutes                                     D      5%        1790 cSt  1200 cSt                                                                               Cloudy - 10                                                                    minutes                                     Compar-                                                                               0%        .sup. 1470 cSt.sup.1                                                                     .sup. 1220 cSt.sup.2                                                                   Cloudy                                      ison                                                                           ______________________________________                                          .sup.1 at 30 minutes                                                           .sup.2 at 1 hour                                                         

Entries C and D behave similarly to decene dimer PAO samples derived from 1-butanol/1-propanol co-catalyzed reactions (see "Comparison" in Table 4 which is a hydrogenated dimer derived from a BF₃ /1-propanol catalyzed reaction), i.e. the KV₋₅₄° C. values were initially high and gradually decreased with time while the mixture became cloudy. The cloud point of a commercially available 2.0 cSt PAO fluid, which consisted of very pure decene dimer, was -57° C. compared to a cloud point of <-70° C. for a 2-methoxyethanol generated dimer of the invention. These results demonstrate that the dimer products of the invention have significantly improved physical properties caused by a difference in composition from prior 1-decene dimer compositions.

EXAMPLE 11

1-Octene (750.0 grams, 6.70 moles) and 2-methoxyethanol (5.09 grams, 67.0 mmoles) were charged into the reactor which was then assembled and purged with N: with gentle agitation for 30 minutes. During this time the vessel was heated to 45° C. with the circulating system. The stirring rate was increased (rpm not measured) and BF₃ was introduced into the reactor via a sparge tube located below the surface of the liquid. After a brief (5-10 seconds) purge, the system was pressurized to 10 psig with BF₃. An exotherm occurred which reached a maximum temperature of 64° C. at ˜15 minutes.

The reaction was stopped by venting the BF₃ through a 10% NaOH scrubber and then quenching with 5% aqueous NaOH (100 mL). The reaction mixture was separated from the quenching medium, washed several times with water, allowed to settle, and filtered through filter paper.

The product contained 5% C₈, 64% C₁₆, 25% C₂₄, and 6% C₃₂ (normalized gas chromatography area percent).

The crude oligomerization product (1200 g) was hydrogenated in a 2-liter autoclave using a Ni/Kieselguhr catalyst (48 g) at 200° C. and 500 psig H₂ for 2 hours. After cooling, the product was filtered through filter-aid to give the crude hydrogenated product. The distillation was carried out at 1.5 mm Hg and the fraction boiling at 107°-120° C. was collected to give 535 g (1071 g feed) of pure hydrogenated octene dimer. The physical properties were as follows:

    ______________________________________                                         KV.sub.100° C.                                                                        1.09         cSt                                                 KV.sub.40° C.                                                                         2.69         cSt                                                 KV.sub.-40° C.                                                                        71.0         cSt                                                 Pour point    <-65° C.                                                  Flash point   122°  C.                                                  ______________________________________                                    

The target specifications for an IEC 296 - Class III and IIIA transformer fluid are:

    ______________________________________                                         KV.sub.40° C.                                                                         3.5         cSt max                                              KV.sub.-40° C.                                                                        150         cSt max                                              Pour point    -60° C. max                                               Flash point   95°  C. min                                               ______________________________________                                    

In such use the fluid is contained in an electrical apparatus, i.e. a power transformer. The fluid surrounds an electrical component in the apparatus and acts as an electrical insulating and heat removal medium.

The physical properties of the octene dimer exceeded the transformer fluid specifications and demonstrated excellent low temperature performance.

The dimer oils of the invention can be used neat in various heat transfer, insulating and lubricant applications, and when used in insulating, functional fluid and/or lubricating oil applications such as, for example, electro erosion, high speed aluminum cold rolling, transformer and switchgear oil, shock absorber, brake, hydraulic textile covering and spindle fluids, drilling muds and the like, their properties can be enhanced by the use of conventional oil additives in total amounts of up to about 25 weight percent and preferably from about 0.1 to 20 weight percent. Such additives include, for example, dispersants, anti-oxidants, anti-wear agents, anti-foam, corrosion inhibitors, detergents, seal swell agents, etc. These types of additives are well known in the art. Some examples of such additives are zinc dialkyl-dithiophosphates, calcium aryl sulfonates, overbased calcium aryl sulfonates, barium phenates, barium oxide neutralized reaction products of phosphorus pentasulfide and terpenes or high molecular weight olefins, hindered alkyl phenols, methylene-bis-dialkyl phenols, dibutyl tin sulfide, dibutyl hydrogen phosphonate, tri-cresyl-phosphate, high molecular weight alkyl succinimides of ethylene-polyamines such as tetraethylene-polyamine, sulfur-bridged alkyl phenols, sulfurized fatty acid esters and amides, silicones, dialkylesters, and the like. Mixtures of the C₈ to C₁₀ dimer oils in any proportions can be used. The dimer compositions can contain minor amounts of higher oligomers (trimer, tetramer, etc.) but preferably contain at least 60 weight percent and more preferably at least 75 weight percent of dimers. The dimer oils can be used as additive oils or as base oils and in blends with mineral oils and with other synthetic oils such as, for example, synthetic esters. 

What is claimed is:
 1. A heat transfer, lubricating, and/or insulating fluid composition which comprises (i) a synthetic oil selected from the group consisting of 1-octene dimer, 1-decene dimer, codimer of 1-octene dimer further consists of a mixture of C₁₆ H₃₂ isomers, which mixture includes 7-methylpentadecene isomers, provided that said mixture contains less than about 2.5 weight percent of said 7-methylpentadecene isomers based on the weight of said mixture, (b) said 1-decene dimer further consists of a mixture of C₂₀ H₄₀ isomers, which mixture includes 9-methylnonadecene isomers, provided that said mixture contains less than about 2.5 weight percent of said 9-methylnonadecene isomers based on the weight of said mixture, and (c) said co-dimer further consists of a mixture of C₁₈ H₃₆ isomers, which mixture includes C₁₈ H₃₆ isomers selected from the group consisting of 7-methylpentadecene, 9-methylheptadecene isomers, and mixtures thereof, provided that said mixture contains less than about 2.5 weight percent of said 7-methylpentadecene and 9-methylheptadecene isomers based on the weight of said mixture, and (ii) from about 0.1 to 2.5 weight percent of fluid composition of one or more oil additives.
 2. The fluid composition of claim 1 wherein said oil additives are selected from dispersants, antioxidants, anti-wear agents, anti-foam agents, corrosion inhibitors, detergents and seal swell agents.
 3. The fluid composition of claim 1 wherein said synthetic oil is hydrogenated so as to provide C₁₆ H₃₄ isomers containing less than about 2.5 weight percent of 7-methylpentadecane, C₂₀ H₄₂ isomers containing less than about 2.5 weight percent of 9-methylnonadecane and C₁₈ H₃₈ isomers containing less than about 2.5 weight percent of 7-methylheptadecane and/or 9-methylheptadecane.
 4. The fluid composition of claim 3 wherein said C₁₆ H₃₄ isomers contain less than about 0.5 weight percent 7-methylpentadecane, said C₂₀ H₄₂ isomers contain less than about 0.5 weight percent 9-methylnonadecane and said C₁₈ H₃₈ isomers contain less than 0.5 weight percent 7-methylheptadecane and/or 9-methylheptadecane.
 5. The fluid composition of claim 3 wherein said synthetic soil consists of C₁₆ H₃₄ isomers.
 6. The fluid composition of claim 2 wherein said synthetic oil consists of C₂₀ H₄₂ isomers.
 7. The fluid composition of claim 2 wherein said synthetic oil consists of C₁₈ H₃₈ isomers.
 8. The fluid composition of claim 2 wherein said synthetic oil consists of C₁₆ H₃₄, C₁₈ H₃₈ and C₂₀ H₄₂ isomers. 